| Matches by round |
| 1 2 3 4 5 6 7 8 |
| Match list: | By round By date Latest |
| R | Date | Home | Score | Away | HT | >2.5 | HT | FT | Time | Rating | >2.5 | |
| 4 | 06/11/2007 | Celtic Glasgow | 0 - 0 | Benfica | 0-0 | No | X | X | 20:45 | 0 | No | |
| 4 | 06/11/2007 | Chakhtior Donetsk | 1 - 0 | Milan AC | 1-0 | No | 1 | 1 | 20:45 | 0 | No | |
| 4 | 06/11/2007 | FC Porto | 2 - 1 | Marseille | 2-0 | Yes | 1 | 1 | 20:45 | 0 | No | |
| 4 | 06/11/2007 | Lazio Rome | 0 - 2 | Werder Brême | 0-1 | No | 2 | 2 | 20:45 | 0 | No | |
| 4 | 06/11/2007 | Liverpool | 2 - 1 | Besiktas | 1-0 | Yes | 1 | 1 | 20:45 | 0 | No | |
| 4 | 06/11/2007 | Olympiakos Le Pirée | 2 - 1 | Real Madrid | 0-0 | Yes | X | 1 | 20:45 | 0 | No | |
| 4 | 06/11/2007 | Schalke 04 | 8 - 0 | Chelsea | 2-0 | Yes | 1 | 1 | 20:45 | 0 | No | |
| 4 | 06/11/2007 | Valence CF | 0 - 0 | Rosenborg Trondheim | 0-0 | No | X | X | 20:45 | 0 | No | |
| 4 | 07/11/2007 | FC Barcelona | 4 - 2 | Glasgow Rangers | 3-1 | Yes | 1 | 1 | 20:45 | 0 | No | |
| 4 | 07/11/2007 | Fenerbahçe | 4 - 2 | PSV Eindhoven | 2-2 | Yes | X | 1 | 20:45 | 0 | No | |
| 4 | 07/11/2007 | Inter Milan | 4 - 0 | CSKA Moscow | 2-0 | Yes | 1 | 1 | 20:45 | 0 | No | |
| 4 | 07/11/2007 | Lyon | 0 - 3 | VfB Stuttgart | 0-0 | Yes | X | 2 | 20:45 | 0 | No | |
| 4 | 07/11/2007 | Manchester United | 2 - 2 | Dynamo Kiev | 1-1 | Yes | X | X | 20:45 | 0 | No | |
| 4 | 07/11/2007 | Slavia Prague | 2 - 0 | Arsenal | 2-0 | No | 1 | 1 | 20:45 | 0 | No | |
| 4 | 07/11/2007 | Sporting CP | 2 - 0 | AS Roma | 2-0 | No | 1 | 1 | 20:45 | 0 | No | |
| 4 | 07/11/2007 | Steaua Bucarest | 0 - 0 | FC Séville | 0-0 | No | X | X | 20:45 | 0 | No |